Well I was bored the other day and, like you do, got to thinking about which Windows functions are the most popular among the executable image files in system32. So I made this little dependency walker type thingymabob that can list imported and exported data/functions for 32bit images. It works with single files or directories (optionally recursing into subdirs) and if you're as nosey as I am, you can get a vector of the x most popular functions imported.
Anyhoo, the code is attached as there's a few files. It's quite heavily commented for me so I think it's followable. Since there's no way I'm doing exercises from a book or writing an article, consider this my small offering unto the general "how do I read an import table" populous

Sample output:
d:\windows\system32\chcfg.exe imports these functions:
From advapi32.dll
RegCloseKey
RegOpenKeyA
RegQueryValueExA
From dsound.dll
DirectSoundCreate
DirectSoundEnumerateA
From kernel32.dll
DeviceIoControl
LocalAlloc
LocalFree
GetLastError
CloseHandle
CreateFileA
GetCPInfo
FreeEnvironmentStringsA
GetModuleFileNameA
SetStdHandle
SetFilePointer
FlushFileBuffers
LoadLibraryA
HeapReAlloc
VirtualAlloc
HeapAlloc
GetStringTypeW
ExitProcess
TerminateProcess
GetCurrentProcess
GetCommandLineA
GetVersion
GetProcAddress
GetACP
GetOEMCP
WideCharToMultiByte
MultiByteToWideChar
LCMapStringA
LCMapStringW
UnhandledExceptionFilter
GetStringTypeA
GetStartupInfoA
FreeEnvironmentStringsW
GetEnvironmentStrings
GetEnvironmentStringsW
SetHandleCount
GetStdHandle
GetFileType
HeapDestroy
HeapCreate
VirtualFree
HeapFree
RtlUnwind
WriteFile
From setupapi.dll
SetupDiGetClassDevsA
SetupDiEnumDeviceInfo
SetupDiGetDeviceInstanceIdA
SetupDiDestroyDeviceInfoList
SetupDiEnumDeviceInterfaces
SetupDiGetDeviceInterfaceDetailA
From user32.dll
GetWindowTextA
SendMessageA
RegisterWindowMessageA
EnumWindows
Oh for anybody wondering about the most popular, this is what I got for system32 on my XP SP2:
The most popular imports are:
kernel32.dll - GetLastError 1077 times imported
kernel32.dll - GetCurrentThreadId 1012 times imported
kernel32.dll - GetCurrentProcess 1007 times imported
kernel32.dll - CloseHandle 953 times imported
kernel32.dll - GetTickCount 949 times imported
kernel32.dll - GetCurrentProcessId 948 times imported
kernel32.dll - TerminateProcess 947 times imported
advapi32.dll - RegCloseKey 929 times imported
kernel32.dll - GetProcAddress 907 times imported
kernel32.dll - UnhandledExceptionFilter 901 times imported